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. 2023 May 10;123(10):6668–6715. doi: 10.1021/acs.chemrev.2c00728

Figure 14.

Figure 14

Effect of IL mixtures from classical DFT. (a) Schematics of micro- and mesopores and a mixture of ionic liquids. (b) Ion selectivity and (c) surface charge as a function of the bulk fraction x of [BF4]– in a mixture of [EMIM]+, [TFSI]–, and [BF4]– for micro- and mesopores. Reproduced with permission from ref (192). Copyright 2017 American Physical Society. (d) Ion selectivity as a function of applied potential difference with respect to the bulk electrolyte for a few pore widths and the same IL mixture as in the other panels. Reproduced with permission from ref (193). Copyright 2017 AIP Publishing. (e) Integral capacitance as a function of the pore width H in a mixture of [EMIM]+, [TFSI]–, and [BF4]– for a few molar fractions of [BF4]–. (f) Integral capacitance as a function of the bulk fraction x of [BF4]– in a mixture of [EMIM]+, [TFSI]–, and [BF4]– for a few applied potential differences and pore width 0.8 nm. Reproduced with permission from ref (194). Copyright 2018 Elsevier.