Table 2. Calculated 19F–M Distances in Isomeric Gd(III) Complexes of La-ca.
|
19F–M distance |
|||
|---|---|---|---|
| form | La (Å) | Lb (Å) | Lc (Å) |
| E | 6.88 | 9.01 | 12.20 |
| Z–H+ | 7.61 | 12.93 | 13.08 |
| absolute change | –0.73 | –3.92 | –0.88 |
The distances were calculated from DFT-optimized structures.