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. 2023 May 31:1–14. Online ahead of print. doi: 10.1007/s10008-023-05548-0

Table 2.

Concepts related to electrochemistry which may form part of the 11–18 curriculum in high schools worldwide

Concept Illustration
Reactivity series Simple list of the relative reactivity of metals (perhaps including carbon and hydrogen)
Metal displacement reactions Use of a simple reactivity series of metals to predict displacement reactions, e.g. metal + metal salt
Redox in terms of electrons OIL RIG definition
Half equations Construction of simple half equations requiring balancing of atoms and electrons (not inclusion of H+/OH/H2O)
Electrolysis of molten salts Electrolysis of molten salts
Electrolysis of solutions Electrolysis of soluble salts, e.g. sodium chloride
Faraday calculations F = Le, where F is the Faraday constant, L is the Avogadro constant, and e is the charge on an electron (in terms of the number of coulombs it carries)
2 different metals + electrolyte = voltage Simple electrochemical cell set up with 2 different metals in an electrolyte producing a voltage
Fuel cells A fuel cell as a device that generates electricity by a chemical reaction. Equations, advantages and disadvantages
Electrochemical series Electrochemical series as a list of reduction equations together with their reduction potentials
Standard hydrogen electrode The use of the Standard Hydrogen Electrode (S.H.E.) as a standard (E0 = 0.00 V), set up and conditions
Ecell calculations E0cell = E0red − E0oxid and related variations
Nernst eqn Relating the effective concentrations of the components of a cell reaction to the standard cell potential. Either in the general form for all temperatures or shortened form at 298 K
Context: extraction of metals Extraction of metals relying on the relative reactivity of elements (e.g. reduction using carbon). Electrolysis of metals with higher reactivities
Context: electroplating Use of electrolysis to electroplate materials, e.g. for decoration or for desirable properties
Context: pH probe Understanding that a pH probe works by measuring the electrical potential produced by the solution and using the potential difference to determine the pH
Context: corrosion Sacrificial protection as a method of preventing corrosion
Context: others Alcosensors, electrochemistry for water treatment