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. 2023 May 3;14(21):5577–5592. doi: 10.1039/d3sc01562a

Selected interatomic distances (Å) and angles (deg) of the Bbim2−-bridged complexes, 1-Lna.

1-Ln Gd Tb Dy
C2–C2′ 1.454(5) 1.447(3) 1.455(4)
Av. Ln–N 2.440(4) 2.428(3) 2.423(2)
Ln–Ln 6.239(1) 6.215(1) 6.203(3)
Cnt–Ln–Cnt 138.0(1) 138.0(1) 138.8(1)
Ln1–N1–N2–Ln2 0.1(1) 0.1(1) 11.8(3)°
N1–Ln–N1′ 72.0(1) 72.4(1) 72.3(1)
a

Cnt = centroid of the pentamethylcyclopentadienyl ring.