Selected interatomic distances (Å) and angles (deg) of the Bbim2−-bridged complexes, 1-Lna.
1-Ln | Gd | Tb | Dy |
---|---|---|---|
C2–C2′ | 1.454(5) | 1.447(3) | 1.455(4) |
Av. Ln–N | 2.440(4) | 2.428(3) | 2.423(2) |
Ln–Ln | 6.239(1) | 6.215(1) | 6.203(3) |
Cnt–Ln–Cnt | 138.0(1) | 138.0(1) | 138.8(1) |
Ln1–N1–N2–Ln2 | 0.1(1) | 0.1(1) | 11.8(3)° |
N1–Ln–N1′ | 72.0(1) | 72.4(1) | 72.3(1) |
Cnt = centroid of the pentamethylcyclopentadienyl ring.