Selected interatomic distances (Å) and angles (deg) of the Bbim3−˙ radical-bridged complexes, 2-Lna.
2-Ln | Gd | Tb | Dy |
---|---|---|---|
C2–C2′ | 1.408(4) | 1.410(6) | 1.403(7) |
Av. Ln–N | 2.390(3) | 2.383(4) | 2.369(4) |
Ln–Ln | 6.100(1) | 6.096(1) | 6.060(1) |
Av. Cnt–Ln–Cnt | 135.8(2) | 135.8(2) | 135.3(2) |
Ln1–N1–N2–Ln2 | 21.7(4)/29.1(4) | 18.5(5)/26.3(5) | 15.5(5)/22.8(5) |
N1–Ln–N1′ | 74.3(1)/75.3(1) | 74.1(1)/75.2(1) | 75.4(1)/75.6(1) |
Cnt = centroid of the pentamethylcyclopentadienyl ring.