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. 2023 May 3;14(21):5577–5592. doi: 10.1039/d3sc01562a

Selected interatomic distances (Å) and angles (deg) of the Bbim3−˙ radical-bridged complexes, 2-Lna.

2-Ln Gd Tb Dy
C2–C2′ 1.408(4) 1.410(6) 1.403(7)
Av. Ln–N 2.390(3) 2.383(4) 2.369(4)
Ln–Ln 6.100(1) 6.096(1) 6.060(1)
Av. Cnt–Ln–Cnt 135.8(2) 135.8(2) 135.3(2)
Ln1–N1–N2–Ln2 21.7(4)/29.1(4) 18.5(5)/26.3(5) 15.5(5)/22.8(5)
N1–Ln–N1′ 74.3(1)/75.3(1) 74.1(1)/75.2(1) 75.4(1)/75.6(1)
a

Cnt = centroid of the pentamethylcyclopentadienyl ring.