Table 3. Hyperpolarizability Values for DHAs and VHFs (Electron-Donating Groups).
no. | substituents | DHA | VHF | no. | substituents | DHA | VHF |
---|---|---|---|---|---|---|---|
1 | 8a-PH2 | 1.40 | 11.09 | 31 | 8a-CH2NH2 | 1.60 | 9.48 |
2 | 8-PH2 | 1.37 | 10.71 | 32 | 8-CH2NH2 | 1.16 | 8.54 |
3 | 7-PH2 | 0.70 | 11.37 | 33 | 7-CH2NH2 | 1.38 | 13.80 |
4 | 6-PH2 | 2.17 | 11.96 | 34 | 6-CH2NH2 | 3.36 | 13.53 |
5 | 5-PH2 | 2.08 | 12.40 | 35 | 5-CH2NH2 | 1.18 | 13.81 |
6 | 4-PH2 | 1.83 | 12.25 | 36 | 4-CH2NH2 | 0.73 | 11.10 |
7 | 8a-OMe | 0.99 | 10.05 | 37 | 8a-CH2F | 1.54 | 9.26 |
8 | 8-OMe | 2.65 | 4.44 | 38 | 8-CH2F | 1.27 | 11.07 |
9 | 7-OMe | 2.74 | 13.40 | 39 | 7-CH2F | 1.39 | 13.61 |
10 | 6-OMe | 9.09 | 16.30 | 40 | 6-CH2F | 1.32 | 14.41 |
11 | 5-OMe | 4.26 | 15.59 | 41 | 5-CH2F | 0.84 | 14.80 |
12 | 4-OMe | 2.49 | 15.53 | 42 | 4-CH2F | 1.35 | 11.94 |
13 | 8a-NHMe | 1.42 | 11.04 | 43 | 8a-CH2Cl | 1.31 | 12.53 |
14 | 8-NHMe | 4.91 | 13.01 | 44 | 8-CH2Cl | 1.20 | 10.65 |
15 | 7-NHMe | 3.32 | 18.19 | 45 | 7-CH2Cl | 0.53 | 14.56 |
16 | 6-NHMe | 14.10 | 15.02 | 46 | 6-CH2Cl | 0.41 | 12.64 |
17 | 5-NHMe | 5.45 | 13.20 | 47 | 5-CH2Cl | 0.55 | 16.01 |
18 | 4-NHMe | 4.26 | 7.74 | 48 | 4-CH2Cl | 0.98 | 11.67 |
19 | 8a-NMe2 | 1.53 | 4.28 | 49 | 8a-CH2Br | 1.12 | 12.01 |
20 | 8-NMe2 | 4.17 | 6.08 | 50 | 8-CH2Br | 1.09 | 9.52 |
21 | 7-NMe2 | 4.08 | 16.47 | 51 | 7-CH2Br | 1.20 | 13.56 |
22 | 6-NMe2 | 14.75 | 19.48 | 52 | 6-CH2Br | 2.99 | 12.00 |
23 | 5-NMe2 | 6.99 | 18.26 | 53 | 5-CH2Br | 2.46 | 15.76 |
24 | 4-NMe2 | 3.74 | 19.48 | 54 | 4-CH2Br | 2.64 | 11.86 |
25 | 8a-CH2OH | 1.68 | 7.40 | 28 | 6-CH2OH | 1.71 | 15.91 |
26 | 8-CH2OH | 1.54 | 10.56 | 29 | 5-CH2OH | 2.18 | 13.81 |
27 | 7-CH2OH | 2.24 | 12.85 | 30 | 4-CH2OH | 1.63 | 11.64 |