Table 1. Scaling Dependencies of the Pump-Probe Signal (ΔOD) for the Competitive Absorber Model in the Low Fluence Limita.
| Low OD (<0.1)b | High OD (>0.5) | |
|---|---|---|
Inverse Beam Waist (
|
Quadratic | Quadratic |
| Analyte Molar Absorptivity(a) | Quadratic | Linear |
| Pump Energy (Resonant Bandwidth) | Linear | Linear |
| Concentration of Analyte(a) | Linear | Bounded-Exponential |
| Path Length(T) | Linear | Bounded-Exponential |
| Solvent Molar Absorptivity | Hyperbolic Decay | Hyperbolic Decay |
