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. 2023 May 18;127(21):4694–4707. doi: 10.1021/acs.jpcb.3c01270

Table 1. Scaling Dependencies of the Pump-Probe Signal (ΔOD) for the Competitive Absorber Model in the Low Fluence Limita.

  Low OD (<0.1)b High OD (>0.5)
Inverse Beam Waist (Inline graphic Quadratic Quadratic
Analyte Molar Absorptivity(a) Quadratic Linear
Pump Energy (Resonant Bandwidth) Linear Linear
Concentration of Analyte(a) Linear Bounded-Exponential
Path Length(T) Linear Bounded-Exponential
Solvent Molar Absorptivity Hyperbolic Decay Hyperbolic Decay
a

(a) Distinguishes limits of absorption relative to OD of analyte and (T) distinguishes limits of absorption relative to OD of analyte + solvent.

b

Bold text highlights canceling effects between the beam waist and optimal path length in the limiting case of weak absorption (section 5.4).