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. Author manuscript; available in PMC: 2023 Jun 24.
Published in final edited form as: Science. 2022 May 26;376(6600):1481–1487. doi: 10.1126/science.abq3048

Fig. 4. Syntheses of natural products.

Fig. 4

(A) Total synthesis of Myrotheciumone A. *Yields based on reactive diastereomers of 61 (see Supplementary Material p. S118 for detailed analysis). †Relative configurations are shown as the synthesis is racemic. (B) Synthesis of Pedicellosine. ‡Isolated as the carboxylic acid. mCPBA = meta-Chloroperoxybenzoic acid, TMSOTf = Trimethylsilyl trifluoromethanesulfonate, EDCI = 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide, DMAP = 4-Dimethylaminopyridine.