Table 1.
Species | Concentration | k•OH (M − 1s − 1) | Contribution to •OH scavenging |
Refs. |
---|---|---|---|---|
Free chlorine | 3 mg/L as Cl2 | 2.0 × 109 HOCl, 8.8 × 109 OCl− |
71% | 2006 Anastasio and Matthew, 2006 |
Monochloramine | 2 mg/L as Cl2 | 1.0 × 109 | 23% | Anastasio and Matthew, 2006 |
Dichloramine | 1.5 mg/L as Cl2 | 6.2 × 108 | 6% | Anastasio and Matthew, 2006 |
Nitrate | 0.8 mg/L as N | 4.0 × 105b | < 1% | Yin et al. 2020b |
Nitrite | Variablea | 1.1 × 1010 | Variablea | Yin et al., 2020 |
M − 1s−1 = per molar per second.
Nitrite is likely to be present only in some systems with UV-H2O2, since free chlorine quickly converts nitrite to nitrate.
This reaction rate coefficient is reported in a secondary source from an ambiguous primary source, but evidence suggests that the rate is negligible.