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. 2023 Jun 7;13(25):17130–17142. doi: 10.1039/d3ra02170j

IIPPs for each layer of the PSC collected from ref. 13.

Parameters FTO SnO2 FA0.85Cs0.15Pb (I0.85Br0.15)3 Spiro-OMeTAD Au
Thickness (t) in nm 500 70 350 165
Band gap (Eg) in eV 3.5 3.5 1.59 2.9
Electron affinity (χ) in eV 4 4 4.09 2.2
Dielectric permittivity (εr) 9 9 6.6 3
CB effective density of states (Nc) in cm−3 2.2 × 1018 2.2 × 1017 2 × 1019 2.2 × 1018
VB effective density of states (Nv) in cm−3 2.2 × 1018 2.2 × 1017 2 × 1018 2.2 × 1018
Electron thermal velocity (Ve) in cm s−1 1 × 107 1 × 107 1 × 107 1 × 107
Hole thermal velocity (Vh) in cm s−1 1 × 107 1 × 107 1 × 107 1 × 107
Electron mobility (μe) in cm2 V−1 s−1 20 20 8.16 0.0001
Hole mobility (μh) in cm2 V−1 s−1 10 10 2 0.0001
Shallow uniform acceptor density (NA) in cm−3 0 0 1.3 × 1016 1.3 × 1018
Shallow uniform donor density (ND) in cm−3 1 × 1015 1 × 1015 1.3 × 1016 0
Defect density (Nt) in cm−3 1 × 1018 1 × 1018 4 × 1013 1 × 1015
Amphoteric defect density (ADD) in cm−3 2 × 1015
Work function (φ) in (eV) 5.3