Table 3.

Scope of Aryl and Heteroaryl Iodides^{a, b, c}

^aConditions: 1b (0.1 mmol, 1.0 equiv), Aryl Iodide (2.0 equiv), Pd(OAc)₂ (10 mol%), TDG1 (30 mol%), L12 (60 mol%), AgTFA (3.0 equiv) and ClCH₂COOH (1.5 equiv) in HFIP (0.5 mL), 120°C, under air, 48 h.

^bConditions: 1j (0.1 mmol, 1.0 equiv), Heteroaryl Iodide (1.5 equiv), Pd(OAc)₂ (10 mol%), TDG1 (30 mol%), L12 (60 mol%), AgTFA (3.0 equiv) and ClCH₂COOH (0.8 equiv) in HFIP (0.4 mL), 120°C, under air, 48 h.

^cIsolated yields

^ddr =1:1.