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. 2023 Jun 9;13(25):17384–17397. doi: 10.1039/d3ra02115g

The average hydrodynamic diameter (dh) and zeta potential (ζ) of silver nanoparticles (AgNPs), stabilized with sodium bis(2-ethylhexyl) sulfosuccinate (AOT-AgNPs), poly(vinylpyrrolidone) (PVP-AgNPs), and citrate (cit-AgNPs) suspended in anionic reactant solution (c(Na2HPO4) = 8 × 10−3 mol dm−3, γ (AgNPs) = 20 mg dm−3, pH 7.4) in the presence or absence of bovine serum albumin (BSA, γ = 200 mg dm−3) and chitosan (Chi, γ = 50 mg dm−3) at 25 °C.

Sample Peak I Peak II Peak III ζ/mV
d h/nm vol% d h/nm vol% d h/nm vol%
Anionic reactant solution
AOT-AgNPs 88.1 ± 1.2 100 −47.3 ± 1.7
PVP-AgNPs 84.1 ± 1.9 100 −18.2 ± 3.5
cit-AgNPs 20.7 ± 6.1 73.3 ± 7.1 85.2 ± 4.2 26.8 ± 7.1 −46.7 ± 2.6
BSA 6.6 ± 0.2 100 −8.4 ± 2.9
Chi 91.5 ± 14.2 100 4.1 ± 1.5
Anionic reactant solution with BSA
AOT-AgNPs 101.7 ± 1.1 100 −25.1 ± 3.7
PVP-AgNPs 100.6 ± 1.3 100 −16.0 ± 7.4
cit-AgNPs 103.3 ± 5.7 100 −28.7 ± 1.7
Anionic reactant solution with Chi
AOT-AgNPs 154.5 ± 2.4 100 2.7 ± 2.7
PVP-AgNPs 161.7 ± 12.0 26.0 ± 2.2 1120.8 ± 38.6 57.0 ± 3.5 4385.3 ± 161.1 17.1 ± 1.8 0.0 ± 2.1
cit-AgNPs 136.4 ± 2.5 100 2.0 ± 2.4