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. 2023 May 24;145(22):12044–12050. doi: 10.1021/jacs.3c01127

Table 1. SVP Values of the N2 Vibrational, Rotational, and the Translational Modes onto the Reaction Coordinatea.

mode   SVP
N2 vibrational mode v 0.131
N2 rotational mode j 0.309
  tx [001] 0.363
N2 transitional mode ty [11̅0] 0.002
  tz 0.257
a

The tx, ty, and tz represent projections of translational modes along the surface azimuth of [001], [11̅0], and surface normal, respectively.