Table 4.
Kinetic parameters (k at 180 °C) calculated from the initial oxidation temperature (IOT) under different heating rates.
| Oil Samples | Treatment | Ea (kJ/mol) | A | k | Linear Regression Equation | R2 |
|---|---|---|---|---|---|---|
| SO | Blank | 84.81 | 2.12 × 109 | 0.90 | y = −4659x + 11.02 | 0.977 |
| RE | 108.23 | 2.69 × 1012 | 0.35 | y = −5945x + 14.23 | 0.991 | |
| BHA + BHT | 99.36 | 1.14 × 1011 | 0.40 | y = −5458x + 12.82 | 0.980 | |
| RO | Blank | 84.63 | 2.50 × 109 | 0.44 | y = −4649x + 11.09 | 0.987 |
| RE | 103.82 | 2.03 × 1011 | 0.22 | y = −5703x + 13.09 | 0.993 | |
| BHA + BHT | 91.84 | 2.64 × 1010 | 0.68 | y = −5045x + 12.15 | 0.979 | |
| CSO | Blank | 65.88 | 3.69 × 108 | 0.94 | y = −3619x + 9.15 | 0.988 |
| RE | 93.84 | 4.49 × 1010 | 0.68 | y = −5155x + 12.39 | 0.986 | |
| BHA + BHT | 74.58 | 4.70 × 108 | 1.19 | y = −4097x + 10.31 | 0.979 | |
| RBO | Blank | 88.69 | 5.09 × 109 | 0.30 | y = −4872x + 11.42 | 0.995 |
| RE | 109.08 | 9.49 × 1011 | 0.25 | y = −5992x + 13.78 | 0.996 | |
| BHA + BHT | 93.86 | 2.30 × 1010 | 0.35 | y = −5161x + 12.10 | 0.982 | |
| CO | Blank | 63.64 | 1.32 × 108 | 0.61 | y = −3496x + 8.69 | 0.994 |
| RE | 79.24 | 7.01 × 108 | 0.51 | y = −4353x + 10.51 | 0.965 | |
| BHA + BHT | 79.23 | 9.25 × 108 | 0.68 | y = −4352x + 10.63 | 0.984 |
Note: Ea, activation energy; A, pre-exponential factor; k, reaction rate constant. SO, soybean oil; RO, rapeseed oil; CSO, cottonseed oil; RBO, rice bran oil; CO, camellia oil.