Table 5.
XRD Crystal data of the different polymeric complexes (Rwp(%) = 6.49, Rexp(%) = 4.31, and RB(%) = 1.03).
| Parameters | Mn(II) Complex | Fe(III) Complex | Ni(II) Complex | Cu(II) Complex |
|---|---|---|---|---|
| Empirical formula | C24H29O28S2Mn | C24H31O29S2FeCl | C24H29O28S2Ni | C24H29O28S2Cu |
| Formula weight | 884.54 | 938.90 | 888.29 | 892.95 |
| Crystal system | Monoclinic | Cubic | Cubic | Cubic |
| a (Å) | 11.197 | 3.9908 | 3.9940 | 5.628 |
| b (Å) | 9.520 | 3.9908 | 3.9940 | 5.628 |
| c (Å) | 6.195 | 3.9908 | 3.9940 | 5.628 |
| Alfa (°) | 90.00 | 90.00 | 90.00 | 90.00 |
| Beta (°) | 99.74 | 90.00 | 90.00 | 90.00 |
| Gamma (°) | 90.00 | 90.00 | 90.00 | 90.00 |
| Volume of unit cell (Å3) | 650.9 | 63.56 | 63.71 | 178.29 |
a, b, and c are the dimensions of the crystal system. Alfa, Beta, and Gamma are the angles of the crystal system of the different complexes.