Table 3.
Summary of rates of carbon monoxide production
| Polymer | Rate (μmol h−1) | Selectivity to CO production (%)a | Rate (μmol h−1 m−2) | Rate with added CuI (μmol h−1) | Rate with added CuI (μmol h−1 m−2) |
|---|---|---|---|---|---|
| pTA | 0.017 ± 0.001 | 87 | 53 ± 3 | 0.033 ± 0.003 | 106 ± 10 |
| pTA-Ph | 0.019 ± 0.001 | 98 | 66 ± 4 | 0.05 ± 0.01 | 175 ± 35 |
| pTA-Th | 0.007 ± 0.001 | 98 | 25 ± 3 | 0.016 ± 0.005 | 55 ± 17 |
| pTA-BT | 0.006 ± 0.001 | 99 | 21 ± 4 | 0.015 ± 0.002 | 37 ± 6 |
| pDHT (SI) | 0.002 ± 0.0006 | – | 10 ± 3 | – | – |
| CNs | 0.002 ± 0.0004 | – | 6 ± 2 | 0.002 ± 0.0005 | 6.6 ± 2 |
| TiO2 | 0.005 ± 0.001 | 96 | 21 ± 5 | – | – |
Rates were calculated from the slope of the curves.
aSelectivity calculated as a percentage of CO detected vs. CH4.