Table 1. Composition and HPLC-Retention Times of the Prepared Peptides.
peptide | P1 | P2 | P3 | P4 | Mw (g/mol) | retention time (min) |
---|---|---|---|---|---|---|
1 | Ph | R | Tbta | R | 788.10 | 9.23 |
2 | Ph | R | Ph | R | 580.74 | 7.61 |
3 | Ph | R | S-BrW | R | 698.67 | 7.98 |
4 | Ph | R | R-BrW | R | 698.67 | 7.62 |
5 | Ph | R | diBrOMe | R | 768.56 | 8.11 |
6 | Ph | R | OMeBip | R | 686.86 | 8.18 |
7 | Ph | R | diBrOMeBip | R | 844.65 | 8.68 |
8 | diBrOMe | R | diBrOMe | R | 956.37 | 8.56 |
9 | BrOMe | R | BrOMe | R | 798.58 | 8.09 |
10 | diBrOH | R | diBrOH | R | 928.32 | 7.77 |
11 | diBrOMe | R | W | R | 807.59 | 8.18 |
12 | diBrOMe | R | BrW | R | 886.49 | 8.43 |
13 | Br-Ind | R | diBrOMe | R | 886.49 | 8.47 |
14 | Ph | R | Bip | KN(Me)3 | 671.91 | 8.19 |
15 | Ph | R | Bip | C5N(Me)3 | 656.90 | 8.55 |
16 | Ph | KN(Me)3 | Bip | R | 671.91 | 8.20 |
17 | Ph | KN(Me)3 | Bip | KN(Me)3 | 686.98 | 8.15 |
18 | Ph | R | diBrOMe | C5N(Me)3 | 768.62 | 8.45 |
19 | diBrOMe | K | diBrOMe | K | 900.35 | 8.47 |
Tri-tert-butyl tryptophan.