Oxidation of 1-phenylethanol with complex 2 in different solventsa.
Entry | Solvent | % conversionb |
---|---|---|
1 | MeCN | 94 |
2 | THF | 35 |
3 | Toluene | 39 |
4 | DMF | 28 |
5 | DMSO | 24 |
6 | CF3CH2OH (TFE) | 68 |
7 | ClCH2CH2Cl (DCE) | 75 |
Reaction conditions: 0.5 mmol substrate, 0.75 mmol TBHP, 1 mol% complex 2, 0.06 mmol 1,3,5-trimethoxybenzene, 0.6 mL solvent, 60 °C, 8 h.
Determined by GC-FID analysis using 1,3,5-trimethoxybenzene as internal standard.