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. 2023 May 11;24(6):2706–2720. doi: 10.1021/acs.biomac.3c00156

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© 2023 The Authors. Published by American Chemical Society

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(A) Specific volume as a function of temperature and degree of ring opening (RO) for dry systems. (B) Density versus degree of ring opening and temperature. (C) Specific volume of systems with TIP3P and TIP4P water models in the 25% water systems. (D) Specific volume when heated from low to high temperature (LH) and thereafter cooled from high to low temperature (HL). (E) Glass-transition temperature (T_g) versus degree of ring opening. (F) Thermal expansion coefficient (below T_g) versus degree of ring opening. Line fits show trends in spectroscopy.