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. 2023 May 31;62(23):8846–8862. doi: 10.1021/acs.inorgchem.3c00311

Table 1. 31P NMR Chemical Shifts (ppm) of Complexes of the Type 2Ma (M = Ni, Pd,14 Pt) in C6D6a.

M anti
syn
  PMe3 μ-2-C6F4PPh2 PMe3 μ-2-C6F4PPh2
Ni –15.0 –3.6 –15.0 –9.4
Pd –19.1 –2.9 –18.7 –8.4
Pt [−24.4 (2700)b] [−5.4 (160)b] –24.6 (2700) –11.1 (90)
a

JPt,P (Hz) coupling constants are given in brackets.

b

31P NMR shifts of the anti-isomer were observed in CDCl3 solution.