Table 2. 31P NMR Chemical Shifts of Complexes of the Type trans-5MM′ (M = Ni, Pd,14 Pt; M′ = Cu, Ag, Au) in CDCl3.
M/M′ | Cu |
Ag |
Au |
|||
---|---|---|---|---|---|---|
PMe3 | μ-2-C6F4PPh2 | PMe3 | μ-2-C6F4PPh2 | PMe3 | μ-2-C6F4PPh2 | |
Ni | –14.4 | 7.2 | –15.1 | 15.9 | –15.9 | 41.8 |
Pda | –16.6 | 3.1 | –17.7 | 11.8 | –17.7 | 37.9 |
Pt | –21.7 | –0.9 | –24.1 | 6.4 | –26.0 | 35.2 |
Measured in CD2Cl2.