. 2023 May 31;62(23):8846–8862. doi: 10.1021/acs.inorgchem.3c00311

Table 5. Energy Difference (ΔE, kcal mol^–1) between the Coordination Isomers of Complexes of the Type 6MM′, 7MM′, and 8MM′ (M = Ni, Pt; M′ = Cu, Ag, Au)^a.

M	M′	cis-6MM′	trans-6MM′	cis–trans-7MM′	cis-cis-7MM′	trans-7MM′	cis-8MM′	trans-8MM′
Ni	Cu	2.17	2.04	2.11	5.97	6.89	12.03	0.00
Pt		0.00	2.32	6.64	7.79	11.79	14.83	11.09
Ni	Ag	0.37	0.00	1.89	6.22	7.43	11.75	1.53
Pt		0.00	2.00	8.08	9.92	13.23	16.89	10.76
Ni	Au	8.05	8.51	0.00	4.60	6.57	15.06	2.58
Pt		1.17	3.37	0.00	2.28	5.99	13.44	7.34

Energy values of the crystallographically characterized isomers are written in italics and bold style.

Table 5. Energy Difference (ΔE, kcal mol–1) between the Coordination Isomers of Complexes of the Type 6MM′, 7MM′, and 8MM′ (M = Ni, Pt; M′ = Cu, Ag, Au)a.