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. 2023 May 30;57(23):8578–8587. doi: 10.1021/acs.est.2c09230

Table 2. Examples of Results from Studies Comparing k600 for CO2 and CH4 in Order of Lower to Higher k600CO2/k600CH4 Ratiosa.

source systems Caq method
k600 (m d–1)
CO2 CH4 CO2   CH4   CO2/CH4
min max min max
McGinnis et al.18 temperate lake Eq Eq 1.97 7.2 3.7 22 0.4
Paranaíba et al.6 three tropical reservoirs Eq Eq 0.1 7.9 0.2 19.1 0.4
Prairie and del Giorgio13 boreal reservoir and lakes Eq Hs 0.1 9.3 0.1 25 0.43
Rantakari et al.19 two boreal lakes Hs Hs 0.5 3.4 1.1 14.5 0.56
Rosentreter et al.20 six mangrove estuaries Eq Eq 1 24 1 28 0.83
Beaulieu et al.5 temperate river Hs Hs 0.2 13.7 0.4 16.8 < 1
Guérin et al.4 tropical reservoir Hs Hs 0.05 1.9 0.1 2.2 1.16
This study four boreal lakes Hs, Eqb Hs 0.1 2.4 0.1 2 1.68
Rosentreter et al.7 mangrove river estuary Eq Hs 0.3 48 0.02 16 2.78
a

Eq and Hs denote measurements with flow through equilibrator and headspace extraction techniques, respectively, for surface water concentrations. The equilibrated chambers technique includes headspace extraction in floating chambers allowed to equilibrate.

b

Equilibrated chambers were used in 21 of the samples from OBJ, and headspace extraction was used in the remaining 11 samples from OBJ and in SOR, BOL, and SOD.