13C (150 MHz) and 1H (600 MHz) NMR data of compounds 2–4 (δ in ppm, CD3OD).
No. | 2 | 3 | 4 | |||
---|---|---|---|---|---|---|
δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | |
1 | 180.9, CH | 9.42, s | 181.1, CH | 9.44, s | 132.9, CH | 7.13, dd (2.1,1.2) |
2 | 133.5, C | 133.7, C | 109.9, CH2 | 6.18, dd (4.1,2.1) | ||
3 | 126.4, CH | 6.99, d (4.0) | 126.0, CH | 6.99, d (4.0) | 120.8, CH | 7.09, dd (4.1,1.2) |
4 | 111.5, CH | 6.27, d (4.0) | 112.7, CH | 6.28, d (4.0) | 127.9, C | |
5 | 144.6, C | 141.4, C | 190.1, C | |||
6 | 56.4, CH2 | 4.64, s | 64.5, CH2 | 4.54, s | 65.4, CH2 | 4.68, s |
1′ | 45.7, CH2 | 4.40, t (7.4) | 46.0, CH2 | 4.37, t (7.7) | 50.0, CH2 | 4.41, t (6.7) |
2′ | 27.5, CH2 | 2.04, tt (7.4, 7.4) | 27.7, CH2 | 2.01, tt (7.7, 7.3) | 29.0, CH2 | 2.00, m |
3′ | 32.0, CH2 | 2.36, t (7.4) | 32.0, CH2 | 2.33, t (7.3) | 34.5, CH2 | 2.17, m |
4′ | 174.7, C | 176.9, C | Unobserved C | |||
![]() |
61.7, CH2 | 4.12, q (7.1) | 66.9, CH2 | 3.55, q (7.0) | ||
![]() |
14.5, CH3 | 1.25, t (7.1) | 15.4, CH3 | 1.20, t (7.0) |