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. 2023 Jun 1;15(23):28300–28309. doi: 10.1021/acsami.3c03962

Table 1. Electrical Properties of Doped Films Comprising Different Amounts of CNFa.

  electrochemical doping
chemical doping
vol % CNF Vth (V) μC* (F cm–1 V–1 s–1) Cmax* (F cm–3) μmax (cm2 V–1 s–1) σ (S cm–1) Np (1026 m–3) μF4TCNQ (cm2 V–1 s–1)
0 –0.20 135 ± 9 162 ± 10 0.83 ± 0.08 24.7 ± 0.3 0.7 ± 0.2 2.1 ± 0.6
3 –0.18 146 ± 15 160 ± 8 0.91 ± 0.10 24.8 ± 3.2 0.8 ± 0.2 2.1 ± 0.7
11 –0.17 123 ± 5 171 ± 11 0.72 ± 0.05 17.9 ± 0.1 1.0 ± 0.3 1.1 ± 0.3
20 –0.20 130 ± 8 197 ± 14 0.65 ± 0.06 19.5 ± 1.4 0.9 ± 0.3 1.4 ± 0.4
a

Electrochemical doping with OECTs (channel width W = 200 μm and channel length L = 20 μm) and EIS devices: threshold voltage Vth, the product of hole mobility and volumetric capacitance μC* from OECT transfer curves (mean and standard error of values extracted from 8–10 devices), maximum dimension-normalized volumetric capacitance Cmax* from EIS (mean and standard error of values extracted from 4 devices), and maximum hole mobility μmax. Chemical doping with F4TCNQ (20 mol % relative to the g42T-T repeat unit): electrical conductivity σ (mean and min–max error of three measurements of the same sample), polaron density Np from analysis of UV–vis spectra (estimated error 30%), and charge-carrier mobility μF4TCNQ.