Table 2. Scope of Aryl and Alkenyl Halides^a.

^aReaction conditions: aryl or alkenyl halide (0.1 mmol), vinyl amide (0.2 mmol), sulfinate precursor (0.2 mmol), L5·NiBr₂ (10 mol %), 4-CzIPN (1 mol %), 15-crown-5 (0.9 mmol), DME [0.025 M], 390 nm 45 W Kessil LED, 0 °C, 48 h. Isolated yields after column chromatography. Enantiomeric ratios (er) were determined by HPLC with a chiral stationary phase.

^bThe corresponding bromides were used as reaction partners.