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. 2023 Jun 19;14:3638. doi: 10.1038/s41467-023-39369-6

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© The Author(s) 2023

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — a Schematic view of LCO with ordered V_O. b Energies of the relaxed structures containing ordered V_O with different in-plane lattice constant. c Projected density of state (PDOS) spectrum for LCO with ordered V_O or dark stripes. d XPS valence band (VB) spectrum excited with a photon energy of 2486.6 eV (left panel) and O K-edge XAS spectrum (right panel) for LCO 25 uc. e Theoretical O K-edge EELS spectra obtained from bright and dark stripes. f The modulation of Co-O bond length as a function of lattice constant.