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. 2023 Jun 5;62(24):9350–9359. doi: 10.1021/acs.inorgchem.3c00251

Table 4. Lattice Parameter Variation of AmVO3 and AmVO4 under Self-Irradiation.

a, Å b, Å c, Å V, Å3 volume variation, % dose (α/g) dpaa
AmVO3 (Pbnm, perovskite)  
5.444 5.590 7.755 235.982   0.01 × 1018 0.0016
5.513 5.661 7.882 245.994 4.2 1.03 × 1018 0.158
AmVO4 (I41/amd, zircon)  
7.294 7.294 6.428 341.952   0.02 × 1018 0.0027
7.243 7.243 6.405 335.964 –1.8 1.02 × 1018 0.134
a

Estimated from the SRIM2013 simulation of displacements produced by an 241Am alpha-decay (i.e., an alpha-particle of 5.486 MeV and a 237Np recoil nucleus of 92 keV) in AmVO3 and AmVO4 yielding dose multiplication factors, d, from dose to displacement per atom of 1700 and 1800, respectively.