Characterization of polyanions for varying σ.
%-Modification | Degree of polymerizationa | No. of modified residues per chain (m) | Linear charge density (σ) | f PEG (%) |
---|---|---|---|---|
0% | 82 | 0 | 1.0 | 9.6 |
PEG-P(Asp-Pr-OH) | ||||
16% | 83 | 13 | 0.84 | 10.4 |
26% | 77 | 20 | 0.74 | 11.4 |
31% | 78 | 24 | 0.69 | 11.5 |
39% | 74 | 29 | 0.61 | 12.3 |
54% | 85 | 46 | 0.46 | 11.4 |
PEG-P(Asp-Bu) | ||||
13% | 77 | 10 | 0.87 | 11.0 |
30% | 82 | 25 | 0.70 | 11.0 |
35% | 82 | 29 | 0.65 | 11.8 |
48% | 84 | 40 | 0.52 | 11.3 |
Degree of polymerization determined by 1H NMR (400 MHz).