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. 2023 May 19;14(24):6608–6620. doi: 10.1039/d3sc00993a

Characterization of polyanions for varying σ.

%-Modification Degree of polymerizationa No. of modified residues per chain (m) Linear charge density (σ) f PEG (%)
0% 82 0 1.0 9.6
PEG-P(Asp-Pr-OH)
16% 83 13 0.84 10.4
26% 77 20 0.74 11.4
31% 78 24 0.69 11.5
39% 74 29 0.61 12.3
54% 85 46 0.46 11.4
PEG-P(Asp-Bu)
13% 77 10 0.87 11.0
30% 82 25 0.70 11.0
35% 82 29 0.65 11.8
48% 84 40 0.52 11.3
a

Degree of polymerization determined by 1H NMR (400 MHz).