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. 2023 Jun 6;59(52):8032–8042. doi: 10.1039/d3cc01620j

Scheme 15. (a) Catalytic scission of C(sp2)–C(sp2) by Rh-carbynoids. (b) Proposed mechanism for the construction of allylic building blocks. (c) Generation of fluorinated cuaternary stereocenters; branched/linear ratio, indicated in parentheses, diastereoselectivity ratio indicated in brackets.

Scheme 15