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. 2023 Jun 9;145(24):13420–13434. doi: 10.1021/jacs.3c03543

Scheme 1. Two Possible Photosubstitution Reactions When Complexes [1a2b](PF6)2 Are Irradiated with Visible Light in Acetonitrile (Sol = CH3CN) or Water (Sol = H2O).

Scheme 1

Reaction A represents the photosubstitution of the sterically hindering ligand (dmbpy or dmphen), and reaction B is the photosubstitution of one of the nonstraining ligands (bpy or phen).