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. 2023 May 16;3(6):1539–1553. doi: 10.1021/jacsau.3c00014

Scheme 15. Synthesis of Bridge-Substituted BCPs, including (a) a Classical Route to Bridge-Substituted [1.1.1]Propellanes, (b) Dihalocarbene Insertion in Bicyclo[1.1.0]butanes, and (c) a Barluenga-Type 1,2-Metallation Approach to Bridge-Substituted BCPs (Qin et al.40).

Scheme 15