Table 1.
No. | Compound name | Retention time | Molecular formula | RI exp | RI lit | Relative abundance (%) |
|||
---|---|---|---|---|---|---|---|---|---|
Spring | Summer | Autumn | Winter | ||||||
1. | α-Thujene | 7.155 | C10H16 | 908 | 906 | 0.64 | – | 0.25 | 0.98 |
2. | α-Pinene | 7.365 | C10H16 | 917 | 917 | 31.41 | 26.34 | 24.68 | 28.69 |
3. | β-Pinene | 8.576 | C10H16 | 962 | 963 | 0.72 | 0.25 | 0.52 | 0.97 |
4. | β-Myrcene | 9.057 | C10H16 | 978 | 978 | – | – | – | 0.45 |
5. | α-Phellandrene | 9.460 | C10H16 | 993 | 994 | 1.03 | 0.32 | 0.64 | 9.51 |
6. | 2-Carene | 9.635 | C10H16 | 999 | 1000 | 0.10 | – | – | – |
7. | 3-Carene | 9.755 | C10H16 | 1003 | 1004 | 0.17 | – | – | 0.38 |
8. | Limonene | 10.115 | C10H16 | 1016 | 1018 | 5.06 | 2.45 | 5.41 | 3.61 |
9. | Eucalyptol | 10.335 | C10H18O | 1022 | 1022 | 44.63 | 66.87 | 58.33 | 46.74 |
10. | γ-Terpinene | 11.165 | C10H16 | 1049 | 1049 | 0.76 | – | – | 0.58 |
11. | α-Terpinolene | 12.067 | C10H16 | 1090 | 1085 | 0.74 | – | – | 0.34 |
12. | Linalool | 12.678 | C10H18O | 1113 | 1113 | – | – | 0.14 | – |
13. | Pinocarveol | 13.633 | C10H16O | 1138 | 1138 | – | 0.23 | 0.45 | 0.42 |
14. | Borneol | 14.297 | C10H18O | 1166 | 1166 | – | – | 0.16 | – |
15. | Terpinen-4-ol | 14.860 | C10H18O | 1168 | 1168 | 1.27 | 0.43 | 0.89 | 0.60 |
16. | α-Terpineol | 15.285 | C10H18O | 1181 | 1181 | 3.62 | 2.67 | 5.97 | 4.05 |
17. | β-Citral | 16.795 | C10H16O | 1232 | 1232 | 0.63 | – | – | – |
18. | α-Citral | 17.680 | C10H16O | 1263 | 1267 | 1.27 | – | – | – |
19. | Eugenol | 20.097 | C10H12O2 | 1366 | 1366 | – | – | 0.20 | – |
20. | Geranyl acetate | 20.410 | C12H20O2 | 1372 | 1377 | – | – | 0.15 | – |
21. | Caryophyllene | 21.797 | C15H24 | 1409 | 1409 | 0.27 | – | 0.18 | 0.26 |
22. | Ledene | 23.652 | C15H24 | 1500 | 1495 | – | – | 0.12 | 0.26 |
23. | δ-Cadinene | 24.455 | C15H24 | 1512 | 1515 | 0.56 | 0.22 | 0.34 | 1.20 |
24. | flavesone | 24.810 | C14H20O4 | 1547 | 1546 | – | – | 0.17 | – |
25. | Spathulenol | 26.066 | C15H24O | 1577 | 1577 | 1.39 | – | 0.14 | 0.50 |
26. | Viridiflorol | 26.121 | C15H26O | 1586 | 1590 | 0.61 | 0.21 | 0.57 | – |
27. | Guaiol | 26.610 | C15H26O | 1596 | 1600 | 0.44 | – | 0.18 | – |
28. | Caryophyllene oxide | 27.010 | C15H24O | 1613 | 1615 | 2.34 | – | 0.20 | 0.39 |
29. | Guaia-3,9-diene-11-ol | 27.790 | C15H24O | 1647 | 1649 | 0.57 | – | – | – |
30. | Neointermedeol | 27.935 | C15H26O | 1653 | 1656 | 0.39 | – | – | – |
31. | Germacrone | 28.850 | C15H22O | 1693 | 1696 | 1.40 | – | 0.32 | – |
Monoterpene hydrocarbons | 40.66 | 29.36 | 31.5 | 45.51 | |||||
Oxygenated monoterpenes | 51.72 | 70.2 | 66.29 | 51.81 | |||||
Sesquiterpene hydrocarbons | 0.83 | 0.22 | 0.64 | 1.72 | |||||
Oxygenated Sesquiterpene | 7.14 | 0.21 | 1.58 | 0.89 | |||||
Total identified (%) | 98.96 | 99.99 | 100 | 99.93 | |||||
Yield (mL/100 gm) | 0.17 | 0.26 | 0.34 | 0.53 |
The major oil components are written in bold.