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. 2023 May 3;14(25):7044–7056. doi: 10.1039/d3sc01627g

Sensitivity data for PETN and substituted PETN derivatives.

Material Impact DH50 (cm) Friction DH50 (N) Electrostatic discharge DH50 (J) DSC (°C) melt/decomp. onset
PETriN-Cl 30.8 ± 2.5 >360 0.0625 66.2/166.3
PEDN-Cl2b >320 >360 0.25 59.5/161.3
PEMN-Cl3b >320 >360 0.25 46.5/154.2
PETriN-Br 30.7 ± 2.4 >360 0.125 91.6/169.2
PEDN-Br2b >320 >360 0.125 73.1/172.6
PEMN-Br3b >320 >360 0.125 56.1/181.0
PETRIN-I 26.6 ± 7.1 >360 0.0625 107.2/167.1
PEDN-I2b >320 >360 0.0625 81.9/178.3
PEMN-I3b >320 N/A N/A 61.5/182.4
PETriN-Me 31.6 ± 1.8 >360 0.0625 51.5/163.4
PEDN-Me2a 90.2 ± 5.5 >360 0.025 N/A/161.4
PETriN-OHa 27 ± 2.0 >360 0.0625 N/A/163.95
PEDN-OH2 112.1 ± 6.1 >360 0.0625 N/A/166.4
PEMN-OH3 >320 >360 0.0625 57.7/162.4
PETN 10.2 ± 0.9 59.5 0.0625 140.9/166.8
a

Material was a liquid and tested on a bare anvil without the use of grit paper.

b

Material was tested five times on impact and friction apparatus at the highest setting without a reaction; no further testing was conducted as these materials were deemed inert.