Table 5. Spectroscopic Constants of the Excited States without and with Spin–Orbit Effect of Cs–Kr System.
| state | Re (a0) | De (cm–1) | Te (cm–1) | ωe (cm–1) | ωexe (cm–1) | Be (cm–1) | ref |
|---|---|---|---|---|---|---|---|
| A2Π (6p) | 7.36 | 406 | 11219 | 32.92 | 1.06 | 0.021609 | this work |
| A2Π1/2 (6p) | 7.31 | 375 | 10881 | 34.80 | 1.07 | 0.021894 | this work |
| 300 | (15) | ||||||
| 7.46 | 163 | 35.1 | (35) | ||||
| 7.20 | 112 | (16) | |||||
| A2Π3/2 (6p) | 7.38 | 406 | 11410 | 32.27 | 0.92 | 0.021494 | this work |
| 350 | (15) | ||||||
| 7.52 | 283 | 38.3 | (35) | ||||
| 7.20 | 439 | (16) | |||||
| B2Σ+ (6p) | 13.45 | 56 | 11569 | 4.74 | 0.91 | 0.022881 | this work |
| B2Σ1/2+ (6p) | 12.84 | 52 | 12844 | 5.65 | 1.18 | 0.031568 | this work |
| 16.2 | 17.1 | (16) | |||||
| 32Σ+ (5d) | 14.60 | 35 | 14592 | 3.91 | 0.11 | 0.005495 | this work |
| 32Σ1/2+ (5d) | 13.65 | 41 | 14633 | 4.88 | 0.23 | 0.006282 | this work |
| 22Π (5d) | 11.16 | 74 | 6.84 | 0.37 | 0.009402 | this work | |
| 22Π1/2 (5d) | 11.08 | 70 | 14534 | 7.21 | 0.83 | 0.009516 | this work |
| 300 | (15) | ||||||
| 7.46 | 163 | 35.1 | (35) | ||||
| 22Π3/2 (5d) | 11.14 | 74 | 14573 | 9.02 | 0.77 | 0.009437 | this work |
| 350 | (15) | ||||||
| 12Δ (5d) | 7.31 | 700 | 13927 | 39.02 | 0.79 | 0.021895 | this work |
| 350 | (15) | ||||||
| 7.37 | 441 | 46.2 | (35) | ||||
| 12Δ3/2 (5d) | 7.32 | 657 | 13887 | 39.02 | 0.81 | 0.021890 | this work |
| 12Δ5/2 (5d) | 7.31 | 700 | 13966 | 39.01 | 0.81 | 0.021902 | this work |
| 42Σ+ (7s) | 7.47 | 461 | 18154 | 27.98 | 0.91 | 0.020985 | this work |
| 8.22 | 322 | 22.3 | (35) | ||||
| 52Σ+ (7p) | 7.11 | 599 | 21433 | 43.71 | 0.92 | 0.023160 | this work |
| 52Σ1/2+ (7p) | 7.15 | 624 | 21499 | 42.44 | 0.83 | 0.022927 | this work |
| 32Π (7p) | 7.24 | 741 | 21292 | 38.79 | 0.69 | 0.022331 | this work |
| 32Π1/2 (7p) | 7.24 | 699 | 21153 | 39.02 | 0.73 | 0.022375 | this work |
| 32Π3/2 (7p) | 7.26 | 734 | 21390 | 38.63 | 0.69 | 0.022231 | this work |
| 62Σ+ (6d) | 7.41 | 220 | 22662 | 26.23 | 2.12 | 0.021341 | this work |
| 42Π (6d) | 7.56 | 670 | 22212 | 37.02 | 0.68 | 0.020485 | this work |
| 22Δ (6d) | 7.11 | 859 | 22023 | 44.78 | 0.81 | 0.023164 | this work |
| 72Σ+ (8s) | 7.27 | 658 | 23775 | 36.34 | 0.84 | 0.022181 | this work |