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. 2023 Mar 23;415(18):4023–4038. doi: 10.1007/s00216-023-04641-7

Table 2.

The selected examples of NP characterization concerning their size and concentration in biological and environmental samples

Analytical technique Type of analytes Matrix Type of measurand LODsize Reference
SP-ICP-MS

Ionic Ce

CeO2 NPS

Animal tissue Particle number concentration and size distribution 15 nm [45]
SP-ICP-MS SeNPs Yeast Particle number concentration and size distribution 18 nm [51]
SP-ICP-MS Polydisperse TiO2 NPS (47Ti and 48Ti) Food Particle size distribution

47Ti 67–85 nm

48Ti 28–36 nm

[53]

SP-ICP-MS

FFF-ICP-MS

AgNPs as nanospheres and nanoplates forms Directly after formation Particle size distribution to monitor particle transformation - [54]
SP-ICP-TOF-MS Nb and TiNb carbonitride (CN) NPs Micro-alloyed steel Particle number concentration, size distribution, presence of agglomerates, multi-elements analysis

NbCNNPs—28 nm

TiNbCNNPs—45 nm

[55]
SP-ICP-MS Hepatitis B virus DNA labeled AuNP Human serum Frequency signals appeared after agglomeration of AuNPs - [64]
IEC-SP-ICP-MS ZnO NPs River water and rainwater Particle number concentration and size distribution 14.3 nm in river water and 17.7 nm in a rainwater [67]
Dispersive suspended microextraction followed by oxidative dissolution back-extraction and AAS Ag in AgNPs Bottled water, river water, effluent wastewater Selective extraction of AgNPs and total concentration of AgNPs - [70]
Solid sampling high-resolution continuum source electrothermal AAS ZnO NPs, Zn2+, and total Zn Cosmetics Speciation analysis - [71]