Values of thermodynamics parameter of micellization for CPB and CPB + LFH (1.982 mmol kg−1) in aq. salt/HDT media.
| Medium | C additive (mmol kg−1) | T (K) | ΔG0m,1 (kJ mol−1) | ΔG0m,2 (kJ mol−1) | ΔH0m,1 (kJ mol−1) | ΔH0m,2 (kJ mol−1) | ΔS0m,1 (J mol−1 K−1) | ΔS0m,2 (J mol−1 K−1) |
|---|---|---|---|---|---|---|---|---|
| H2O | 0 | 293.15 | −48.76 | −27.86 | −86.59 | 37.62 | −129.0 | 223.4 |
| 298.15 | −46.84 | −31.13 | −72.57 | 37.71 | −86.29 | 230.9 | ||
| 303.15 | −45.69 | −32.76 | −59.37 | 35.07 | −45.12 | 223.7 | ||
| 308.15 | −44.39 | −34.60 | −45.74 | 32.10 | −4.39 | 216.4 | ||
| 313.15 | −43.58 | −35.34 | −32.42 | 27.68 | 35.63 | 201.2 | ||
| 318.15 | −42.47 | −37.01 | −18.83 | 23.49 | 74.29 | 190.2 | ||
| 323.15 | −41.60 | −38.07 | −5.708 | 18.31 | 111.1 | 174.5 | ||
| H2O + NaCl | 6.00 | 293.15 | −29.69 | −26.84 | −48.78 | −16.37 | −65.12 | 35.71 |
| 298.15 | −30.83 | −27.41 | −32.16 | −7.152 | −4.455 | 35.71 | ||
| 303.15 | −34.44 | −29.63 | −14.69 | 3.081 | 65.12 | 107.9 | ||
| 308.15 | −42.04 | −30.78 | 8.751 | 14.79 | 164.8 | 147.9 | ||
| 313.15 | −44.70 | −31.86 | 37.78 | 27.44 | 263.4 | 189.4 | ||
| 318.15 | −50.23 | −34.98 | 73.82 | 43.39 | 389.9 | 246.3 | ||
| 323.15 | −54.59 | −37.94 | 111.6 | 61.09 | 514.2 | 306.5 | ||
| H2O + NaOAc | 5.989 | 293.15 | −36.11 | −29.49 | −9.020 | 0.549 | 92.40 | 102.5 |
| 298.15 | −38.56 | −30.56 | −16.08 | 7.790 | 75.41 | 128.6 | ||
| 303.15 | −41.79 | −32.67 | −2.083 | 16.27 | 131.0 | 161.4 | ||
| 308.15 | −43.10 | −34.14 | 13.97 | 25.48 | 185.2 | 193.5 | ||
| 313.15 | −44.86 | −37.25 | 31.30 | 36.99 | 243.2 | 237.1 | ||
| 318.15 | −47.19 | −39.31 | 50.31 | 48.56 | 306.5 | 276.2 | ||
| 323.15 | −51.93 | −41.16 | 73.77 | 60.81 | 389.0 | 315.6 | ||
| H2O + NaBenz | 6.002 | 293.15 | −28.84 | −35.65 | −40.84 | −17.18 | −40.93 | 62.98 |
| 298.15 | −29.71 | −32.68 | −24.75 | −4.100 | 16.60 | 95.86 | ||
| 303.15 | −32.52 | −30.34 | −7.609 | 7.327 | 82.20 | 124.2 | ||
| 308.15 | −34.30 | −30.59 | 13.06 | 18.81 | 153.7 | 160.3 | ||
| 313.15 | −36.82 | −30.77 | 36.53 | 30.39 | 234.2 | 195.3 | ||
| 318.15 | −41.56 | −31.20 | 65.39 | 42.45 | 336.2 | 231.5 | ||
| 323.15 | −45.75 | −31.71 | 96.70 | 53.83 | 440.8 | 264.7 | ||
| H2O + 4-ABA | 5.995 | 293.15 | −45.78 | −36.15 | 3.125 | −21.99 | 166.8 | 48.29 |
| 298.15 | −47.07 | −35.47 | 0.975 | −13.27 | 161.1 | 74.45 | ||
| 303.15 | −47.68 | −33.43 | −1.400 | −3.863 | 152.7 | 97.54 | ||
| 308.15 | −50.05 | −32.55 | −4.141 | 5.224 | 149.0 | 122.6 | ||
| 313.15 | −50.90 | −32.54 | −7.068 | 14.67 | 140.0 | 150.8 | ||
| 318.15 | −51.04 | −31.58 | −10.18 | 23.79 | 128.4 | 174.0 | ||
| 323.15 | −51.22 | −31.06 | −13.44 | 33.24 | 116.9 | 199.0 | ||
| H2O + urea | 1000.12 | 293.15 | −48.39 | −36.38 | −93.97 | 17.24 | −155.5 | 182.9 |
| 298.15 | −47.03 | −36.15 | −87.14 | 15.36 | −134.5 | 172.8 | ||
| 303.15 | −46.12 | −36.11 | −80.00 | 13.52 | −111.8 | 163.7 | ||
| 308.15 | −45.98 | −35.33 | −73.51 | 11.34 | −89.35 | 151.4 | ||
| 313.15 | −45.60 | −35.24 | −66.16 | 9.369 | −65.65 | 142.4 | ||
| 318.15 | −45.56 | −35.21 | −58.83 | 7.376 | −41.72 | 133.8 | ||
| 323.15 | −45.54 | −35.02 | −51.06 | 5.237 | −17.06 | 124.6 |