. 2023 Jul 11;13(30):20709–20722. doi: 10.1039/d3ra02621c

Thermodynamic properties of transfer (free energy (ΔG⁰_m,t), enthalpy (ΔH⁰_m,t) and entropy (ΔS⁰_m,t)) for the CPB + LFH (1.982 mmol kg⁻¹) system in salt/HDT media.

Medium	C _salt/HDT (mmol kg⁻¹)	T (K)	ΔG⁰_m,1,t (kJ mol⁻¹)	ΔH⁰_m,1,t (kJ mol⁻¹⁾	ΔS⁰_m,1,t (J mol⁻¹ K⁻¹)	ΔG⁰_m,2,t (kJ mol⁻¹)	ΔH⁰_m,2,t (kJ mol⁻¹)	ΔS⁰_m,2,t (J mol⁻¹ K⁻¹)
H₂O + NaCl	6.00	293.15	19.07	37.80	63.90	1.021	−53.99	−187.7
		298.15	16.01	40.40	81.83	3.718	−44.86	−162.9
		303.15	11.53	44.79	109.7	3.133	−31.99	−115.8
		308.15	2.352	54.49	169.2	3.812	−17.30	−68.53
		313.15	−1.120	70.21	227.8	3.474	−0.242	−11.87
		318.15	−7.760	92.65	315.6	2.025	19.90	56.19
		323.15	−13.00	117.3	403.1	0.1221	42.78	132.0
H₂O + NaOAc	5.989	293.15	12.65	77.56	221.4	−1.631	−37.07	−120.9
		298.15	8.278	56.49	161.7	0.572	−29.92	−102.3
		303.15	3.903	57.29	176.1	0.091	−18.79	−62.29
		308.15	1.292	59.71	189.6	0.455	−6.615	−22.94
		313.15	−1.286	63.73	207.6	−1.913	9.310	35.84
		318.15	−4.726	69.14	232.2	−2.307	25.07	86.06
		323.15	−10.33	79.48	277.9	−3.094	42.50	141.1
H₂O + NaBenz	6.002	293.15	19.92	45.75	88.09	−7.788	−54.80	−160.4
		298.15	17.13	47.82	102.9	−1.553	−41.81	−135.0
		303.15	13.17	51.76	127.3	2.423	−27.74	−99.50
		308.15	10.09	58.80	158.1	4.008	−13.28	−56.11
		313.15	6.755	68.95	198.6	4.570	2.712	−5.933
		318.15	0.909	84.22	261.9	5.808	18.96	41.33
		323.15	−4.148	102.4	329.8	6.361	35.52	90.24
H₂O + 4-ABA	5.995	293.15	2.984	89.71	295.8	−8.290	−59.61	−175.1
		298.15	−0.232	73.54	247.4	−4.342	−50.99	−156.4
		303.15	−1.990	57.97	197.8	−0.670	−38.93	−126.2
		308.15	−5.658	41.60	153.4	2.042	−26.87	−93.84
		313.15	−7.323	25.355	104.4	2.792	−13.01	−50.45
		318.15	−8.578	8.648	54.14	5.426	0.299	−16.12
		323.15	−9.623	−7.732	5.852	7.006	14.93	24.51
H₂O + urea	1000.12	293.15	0.3780	−7.386	−26.48	−8.362	−9.330	−3.302
		298.15	−0.191	−14.57	−48.23	−4.911	−12.20	−24.44
		303.15	−0.427	−20.63	−66.64	−3.350	−12.27	−29.43
		308.15	−1.588	−27.77	−84.97	−0.731	−12.58	−38.46
		313.15	−2.019	−33.73	−101.3	0.098	−11.08	−35.69
		318.15	−3.090	−40.00	−116.0	1.801	−9.82	−36.51
		323.15	−3.947	−45.35	−128.1	3.050	−7.802	−33.58

Thermodynamic properties of transfer (free energy (ΔG0m,t), enthalpy (ΔH0m,t) and entropy (ΔS0m,t)) for the CPB + LFH (1.982 mmol kg−1) system in salt/HDT media.

Thermodynamic properties of transfer (free energy (ΔG⁰_m,t), enthalpy (ΔH⁰_m,t) and entropy (ΔS⁰_m,t)) for the CPB + LFH (1.982 mmol kg⁻¹) system in salt/HDT media.