Table 2. Statistical Data on SESE = αF + βR Correlations (Equation 3) in Y–R–X Systems, Y = NO2, X = NO2, CN, Cl, H, OH, NH2a.
| Y = NO2 |
Y = O– |
||||||||
|---|---|---|---|---|---|---|---|---|---|
| R | n | α | β | r2 | α/β | α | β | r2 | α/β |
| polyene | 1 | –7.39 | –10.63 | 0.945 | 0.70 | 27.97 | 45.91 | 0.943 | 0.61 |
| 2 | –7.06 | –5.03 | 0.971 | 1.40 | 22.12 | 37.16 | 0.954 | 0.60 | |
| 3 | –5.11 | –3.91 | 0.978 | 1.31 | 18.85 | 29.98 | 0.956 | 0.63 | |
| 4 | –3.87 | –3.36 | 0.975 | 1.15 | 16.28 | 25.26 | 0.958 | 0.64 | |
| 5 | –3.15 | –2.73 | 0.980 | 1.15 | 15.08 | 21.66 | 0.954 | 0.70 | |
| polyyne | 1 | –9.32 | –4.89 | 0.942 | 1.91 | 36.79 | 49.00 | 0.951 | 0.75 |
| 2 | –6.92 | –2.87 | 0.955 | 2.41 | 27.37 | 34.57 | 0.925 | 0.79 | |
| 3 | –5.08 | –2.62 | 0.959 | 1.94 | 21.99 | 26.59 | 0.919 | 0.83 | |
| 4 | –3.96 | –2.37 | 0.969 | 1.67 | 18.55 | 21.62 | 0.927 | 0.86 | |
| 5 | –2.89 | –1.87 | 0.853 | 1.55 | 15.87 | 17.83 | 0.911 | 0.89 | |
| acene | 1 | –4.42 | –4.72 | 0.991 | 0.94 | 16.80 | 31.46 | 0.957 | 0.53 |
| 2 | –2.80 | –3.47 | 0.996 | 0.81 | 12.03 | 23.24 | 0.965 | 0.52 | |
| 3 | –1.90 | –2.31 | 0.995 | 0.82 | 9.41 | 18.20 | 0.966 | 0.52 | |
| 4 | –1.41 | –1.72 | 0.995 | 0.82 | 7.78 | 14.75 | 0.966 | 0.53 | |
α/β is the ratio between coefficients for field (α) and resonance (β) parameters.