Table 3. Reaction of Other Benzophosph-3-yl Triflates 3b–d with Aryl Boronic Acids 4^a,b,c.

^aReaction conditions: 3 (0.134 mmol), 4 (0.16 mmol), K₂CO₃ (0.27 mmol), Pd(PPh₃)₄ (6.7 μmol), DME (1 mL), 110 °C, 24 h.

^bIsolated yields.

^cNumbers in parentheses indicate estimated (in reference to the starting material) yields according to ³¹P NMR.

^dFor fractions that, after purification, were contaminated with up to 5–7% of Ph₃P(O), the yields of products were calculated according to ¹H NMR.

^eReaction was carried out in a 1 mmol scale starting from 0.389 g of 3b, 4n (1.2 mmol), K₂CO₃ (2 mmol), Pd(PPh₃)₄ (0.05 mmol), DME (5 mL), 110 °C, 24 h.

^f8h was contaminated with 2% of 3d according to ¹H NMR.