. 2023 Jun 21;88(13):8674–8689. doi: 10.1021/acs.joc.3c00564

Table 2. ΔH⁰ and ΔS⁰ Values for the 1:βCyD Complexes Formed in Water before Irradiation (∼100% of E-Isomer) and after Irradiation at 365 nm (∼80% of Z-Isomer).

thermodynamic parameter	ΔH⁰ (kJmol^–1)	ΔS⁰ (J K^–1 mol^–1)
E-isomer	–11.1 ± 4.2	+22.1 ± 14.3
Z-isomer	–21.7 ± 4.3	–20.2 ± 14.6

Table 2. ΔH0 and ΔS0 Values for the 1:βCyD Complexes Formed in Water before Irradiation (∼100% of E-Isomer) and after Irradiation at 365 nm (∼80% of Z-Isomer).