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. 2023 Jun 14;123(13):8638–8700. doi: 10.1021/acs.chemrev.3c00101

Table 2. Integrated Hydrogen Areas from the IINS Spectra in Order of Increasing Average Primary Particle Sizea.

Catalyst (sample no.) Morphologyb DN/nmc Relative aread
Pd(20%)/carbon black (2) agg 2.40 1.31
Pd(20%)/activated carbon (1) prim 3.58 1.00
Pd(20%)/carbon black 300 °C (3) agg/prim 6.73 1.65
Pd(20%)/carbon black 400 °C (4) prim 7.74 1.30
a

Reproduced with permission from ref (129) under a Creative Commons Attribution 3.0 Unported License (CC-BY).

b

Morphological differences according to TEM: agg = mostly aggregates, prim = mostly isolated primary particles.

c

Average particle size from statistical determination by TEM.

d

Relative area of the region 350–800 cm–1 of the spectra shown in Figure 16.