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. 2023 Jul 14;14:4210. doi: 10.1038/s41467-023-39848-w

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© The Author(s) 2023

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — a IR spectrum and b NMR spectrum for AA with different oxidation times in 1 M AA solution. c Yield rates of DHA at different reaction times. d Gibbs free energy diagram for different metals at a potential of U = 0 V. e Mechanism of AA reaction. M(Fe, Cu, Co, Ni) and HA^- refer to metal and the dissociation of a hydrogen from AA, respectively. M-HA presents HA^- adsorbed on metal. M-A^{- •} means M-HA lost a proton and an electron.