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. 2023 Jul 2;92(3):193–203. doi: 10.1007/s00280-023-04554-3

Table 2.

Pharmacokinetic parameter estimates for substrates of CYP1A2 (caffeine), CYP2C19 (omeprazole), and CYP3A (midazolam) and their metabolites (paraxanthine, 5-HO, and 1ʹ-HM, respectively) in the presence and absence of adavosertib 225 mg bid (pharmacokinetic analysis set)

Point estimates of the geometric LS mean ratios S + AD/S, % (90% CI) Median tmax, h (range) Mean t½ h (SD) Mean CL/F, L/h (SD) Mean Vz/F, L (SD) Mean MR
AUC AUC0–t Cmax
AUC,
ng·h/mL
AUC0–t,
ng·h/mL
Cmax,
ng/mL
 − AD  + AD  − AD  + AD  − AD  + AD  − AD  + AD  − AD  + AD  − AD  + AD  − AD  + AD
Caffeinea

149.1

(131.3–169.3)

160.8

(143.3–180.5)

103.8

(92.2–116.9)

0.5

(0.3–3.0)

0.7

(0.3–3.0)

6.4

(3.8)

13.5

(6.8)

5.7

(2.5)

3.8

(1.9)

39.3

(15.0)

37.9

(12.1)

NA
Omeprazole

180.2

(145.7–222.9)

198.1

(160.3–244.7)

145.5

(114.0–185.7)

3.0

(0.7–6.0)

3.9

(0.5–8.0)

2.0

(1.0)

2.5

(1.3)

13.3

(10.5)

7.6

(7.3)

28.3

(16.6)

19.8

(10.1)

NA
Midazolam

155.3

(138.6–173.9)

155.2

(140.5–171.5)

138.5

(118.9–161.3)

0.5

(0.2–1.0)

0.5

(0.2–1.0)

5.5

(2.6)

6.6

(3.0)

59.0

(34.3)

39.7

(14.5)

409.9

(211.5)

364.1

(182.7)

NA
Paraxanthineb NC NC

81.2

(74.6–88.5)

8.0

(4.0–11.8)

9.9

(6.0–24.9)

7.0

(2.7)

12.2

(5.4)

NA 0.65 NC 0.54 0.32 0.23 0.16
5-HO

143.0

(123.8–165.0)

148.8

(129.6–170.8)

92.9

(78.6–109.8)

3.0

(0.7–6.0)

4.0

(1.8–7.8)

2.7

(1.7)

4.5

(4.7)

NA 0.50 0.46 0.73 0.50 0.53 0.30
1ʹ-HM

153.5

(131.0–179.8)

158.2

(139.1–180.0)

133.4

(106.5–167.1)

0.5

(0.3–2.1)

0.5

(0.2–1.0)

7.2

(6.1)

7.6

(7.1)

NA 0.41 0.45 0.43 0.44 0.47 0.43

Patient numbers for cocktail without AD (period 1) were: caffeine (AUC: 22; AUC0–t, Cmax, tmax, and t½: 25), omeprazole (AUC and t½: 21; AUC0–t, Cmax, and tmax: 27), midazolam (AUC and t½: 22; AUC0–t, Cmax, and tmax: 23), paraxanthine (AUC: 10; t½: 14; AUC0–t, Cmax, and tmax: 19), 5-HO (AUC: 22; t½: 24; AUC0–t, Cmax, and tmax: 28), and 1'-HM (AUC: 20; t½: 22; AUC0–t, Cmax, and tmax: 24). Patient numbers for cocktail with AD (period 2) were: caffeine (AUC: 8; AUC0–t and t½: 18; Cmax and tmax: 19), omeprazole (AUC and t½: 15; AUC0–t: 18; Cmax and tmax: 20), midazolam (AUC and t½: 18; AUC0–t, Cmax, and tmax: 19), paraxanthine (AUC: 1; t½: 5; AUC0–t: 15; Cmax and tmax: 16), 5-HO (AUC: 13; t½: 17; AUC0–t: 18; Cmax and tmax: 20), and 1'-HM (AUC: 17; t½: 18; AUC0–t, Cmax and tmax: 19). aCaffeine AUC was only reliably characterized in eight patients receiving cocktail with AD in period 2. Caffeine AUC increased in all seven patients with paired data for both periods; results were considered representative of the data. bParaxanthine AUC was only reliably characterized in 10 patients in period 1 (cocktail only) and one patient in period 2 (cocktail + AD); thus, the treatment comparison for AUC was not considered scientifically meaningful. 1ʹ-HM 1ʹ-hydroxymidazolam, 5-HO 5-hydroxyomeprazole, AD adavosertib, AUC area under the plasma concentration–time curve, AUC0–t area under the plasma concentration–time curve from time zero to time of the last quantifiable concentration, CI confidence interval, CL/F apparent clearance, Cmax maximum plasma drug concentration, CYP cytochrome P450, LS least-squares, MR metabolic ratio in relation to parent compound, NA not available, NC not calculable, S + AD/S substrate (or compound) + adavosertib compared with substrate or compound alone, SD standard deviation, t½ plasma terminal half-life, tmax time to reach maximum plasma concentration, Vz/F apparent volume of distribution