Table 1.

Compounds of Rhamnidium elaeocarpum extract by HPLC–DAD–MS/MS.

Peak	RT (min)	UV (nm)	MF	[M−H]−	MS/MS	Compound	References
1	1.2	–	C12H22O11	341.1094		Di-O-hexoside
2	1.5	–	C6H8O7	191.0197	111	Citric acid	44
3	4.5	270	C30H26O14	609.1250	547, 474, 305	Prodelphinidin dimer type B	45
4	4.5	270	C15H14O7	305.0667	261, 219	Gallocatechin	46,47
5	5.2	276	C36H36O18	755.1829	–	Flavonol derivative
6	6.2	275	C30H26O13	593.1301	423, 305	Procyanidin-prodelphinidin dimer B type	48
7	7.9	270	C19H26O13	461.1307		NI
8	8.7	280	C36H36O17	739.1880	435, 273	Procyanidin dimer type B hexoside isomer	49
9	9.0	272	C21H24O11	451.1246	313, 166 161	Epicatechin-3-O-hexoside isomer	49
10	9.3	276	C15H14O7	305.0667	261, 219	Epigallocatechin	47
11	9.7	277	C36H36O17	739.1880	569, 407	Procyanidin dimer type B hexoside isomer	49
12	10.2	280	C30H26O13	593.1301	423, 305	Procyanidin-prodelphinidin dimer type B	48
13	11.1	280	C51H48O22	1011.2564	–	NI
14	11.3	280	C13H24O9	323.1348	298, 165	NI
15	11.5	278	C59H62O33	649.1592*	–	NI
16	11.6	278	C36H36O16	723.1931	553, 407, 255	Procyanidin type B deoxyhexoside	50,51
17	12.6	278	C30H26O12	577.1351	407, 289	Procyanidin dimer type B	49
18	13.0	279	C21H24O10	435.1310	289, 271, 203	Epicatechin deoxyhesoxide
19	13.2	279	C21H22O11	449.1089	–	NI
20	14.1	279	C16H20O10	371.0984	249, 189	NI
21	15.2	279	C16H20O11	387.0933	–	NI
22	16.0	280	C27H32O16	611.1618	–	NI
23	16.4	278	C17H22O10	385.1140	–	NI
24	16.7	278	C34H44O21	787.2324	–	NI
25	17.0	282	C23H39O13	523.2396	–	NI
26	17.5	278	C27H34O16	613.1802	–	NI
27	17.7	278	C17H24O9	531.0828	–	NI
28	17.8	278	C18H25O20	561.0945	–	NI
29	18.4	280	C47H58O29	1085.2978	–	NI
30	18.6	278	C28H40O13	583.2396	–	NI
31	19.3	279	C29H30O16	597.1480	–	NI
32	19.6	278	C41H50O24	925.2622	–	NI
33	20.8	280	C45H54O28	1041.2729	–	NI
34	20.9	280	C28H35O16	627.1931	–	NI
35	21.0	282	C46H53O27	1037.2780	–	NI
36	21.1	280	C54H52O23	1067.2827	–	NI
37	21.3	280	C64H76O40	742.1962*	–	NI
38	22.9	282	C48H56O27	1063.2936	–	NI
39	24.4	280	C19H34O10	421.2079	–	NI
40	31.5	270	C18H33O5	329.2333	–	NI
41	35.8	278, 429	C30H26O8	513.1555	495, 471, 410, 57	karwinaphthopyranone derivative	52
42	36.0	278, 429	C30H26O8	513.1555	495, 471, 410, 57	karwinaphthopyranone derivative	52
43	36.5		C30H24O8	511.1411		NI
44	36.7		C18H30O3	293.2112	–	NI
45	36.8		C34H60O16	723.3809	–	NI
46	37.1		C30H28O8	515.1741	–	NI
47	37.3		C34H44O9	595.2913	–	NI
48	37.9	–	C18H32O3	295.2279	277, 171	( ±)9-hydroxy-10E,12Z-octadecadienoic acid (9-HODE)	53
49	38.4	268, 413	C32H32O8	543.2024	528, 513	karwinaphthopyranone derivative	52
50	38.8	268, 413	C32H32O8	543.2024	528, 513	karwinaphthopyranone derivative	52
51	40.9	–	C37H16O3	507.1027	–	NI
52	41.3	–	C18H30O2	277.2173	–	Fatty acid
53	42.5	–	C18H32O2	279.2330	–	Fatty acid
54	43.7	–	C16H32O2	255.2330	–	Fatty acid
55	44.2	–	C18H34O2	281.2486	–	Fatty acid

RT retention time, MF molecular formula, NI not identified.

*Double charge.