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. 2023 Jul 24;13(32):22234–22249. doi: 10.1039/d3ra03885h

The composition of furan-based copolyesters was determined from 1H NMR and SECa.

Copolymer Composition 1H NMRb SECc
Theoretical wt% [mol%] Calculatedb wt% [mol%] M n [g mol−1] M n [g mol−1] M w [g mol−1] Đ
PHF-DLF 70/30 [86.6/13.4] 67.5/32.5 [85.2/14.8] 17 600 5700 10 700 1.9
POF-DLF 70/30 [85.3/14.7] 68.1/31.9 [84.2/15.8] 19 500 13 700 40 500 3.0
PDF-DLF 70/30 [84.0/16.0] 70.0/30.0 [84.0/16.0] 23 900 19 000 42 600 2.2
PDDF-DLF 70/30 [82.8/17.2] 70.7/29.3 [83.2/16.8] 34 800 20 600 45 700 2.2
a

M n – number average molecular mass, Mw – weight average molecular mass, Đ – dispersity index.

b

Values calculated from 1H NMR.

c

Values determined from SEC.