Skip to main content
. 2023 Jul 24;13(32):22234–22249. doi: 10.1039/d3ra03885h

DSC results for furan-based copolymer seriesa.

Copolymer PHF-DLF POF-DLF PDF-DLF PDDF-DLF
T g [°C] −15 −17 −20 −21
ΔCp [J g−1 °C−1] 0.243 0.288 0.281 0.343
T c [°C] 87 71 27 26
ΔHc [J g−1] 48.29 41.85 30.77 34.86
T cc [°C] 7 −1
ΔHcc [J g−1] 4.77 2.76
T m [°C] 131 127 95 91
ΔHm [J g−1] 44.29 38.24 34.40 36.43
X c [%] 32.8 21.2 17.4 15.7
X c,h [%] 48.6 31.1 24.6 22.2
graphic file with name d3ra03885h-t19.jpg 56.5 50.0 42.3 41.1
a

T g – glass transition temperature; ΔCp – heat capacity at Tg; ΔHm – melting enthalpy; Tm – melting temperature; Tc – crystallization temperature; ΔHc – crystallization enthalpy; Tcc – cold crystallization temperature; ΔHcc – cold crystallization enthalpy; Xc – total crystalline phase content in the polymer calculated from DSC. Xc,h – crystalline phase content in hard segments calculated from DSC. Inline graphic – total crystalline phase content in the polymer calculated from XRD.