Table 1. Selected Bond Distances and Angles for Complexes 1, 2, and 3.
| complex | 1 | 2 |
3 | |
|---|---|---|---|---|
| prefix m of ligand | not applied | m = 1 | m = 2 | not applied |
| Bond Distances (Å) | ||||
| V(1)–O(m1) | 1.923(2) | 1.926(1) | 1.937(1) | 1.894(2) |
| V(m1)–N(m2) | 2.047(2) | 2.071(2) | 2.064(2) | 2.104(2) |
| V(m1)–S(m1) | 2.3524(6) | 2.3434(7) | 2.3500(7) | 2.3519(8) |
| Bond Angles (°) | ||||
| O(m1)–V(1)–O(m1)a | 78.27(9)° | 78.36(6)° | [−O(2)] | 83.3(1)° |
| S(m1)–V(1)–S(m1)a | 108.37(4)° | 112.68(3)° | [−S(12)] | 138.77(5)° |
| N(m2)–V(1)–N(m2)a | 155.1(1)° | 148.04(7)° | [−N(22)] | 125.2(1)° |
| O(m1)–V(1)–S(m1) | 155.6(1)° | 148.9(1)° | 149.5(1)° | 125.3(1)° |
a
Symmetry operators used to generate equivalent atoms: −x+1, y, −z+1/2 for 1, −x+1/2, y, −z+1/2 for 3. For 2, bond angles are given between chemical equivalents atoms O(1)–O(2), S(11)–S(12), and N(12)–N(22).