Table 2. Hammett Parameters for Reduction Potentials of Arylmethanesa.
| ρ | ρ+ | ρ– | |||
|---|---|---|---|---|---|
| Ar3C+/• | per 3σ | 6.0 | 3.5 | ||
| Ar3C•/– | per 3σ | 4.9 | 4.8 | ||
| ArPhCH+/• | per 1σ | 5.6 | |||
| ArPhCH•/– | per 1σ | 7.4 | |||
| ArCH2+/• | per 1σ | 9.3 | |||
| ArCH2•/– | per 1σ | 13.5 | |||
The first two lines are from this work (Table 1 and SI Section 7); the remaining values are from ref (70).