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. 2023 Jul 5;88(14):9893–9901. doi: 10.1021/acs.joc.3c00658

Table 2. Hammett Parameters for Reduction Potentials of Arylmethanesa.

  ρ ρ+ ρ
Ar3C+/• per 3σ 6.0   3.5  
Ar3C•/– per 3σ   4.9   4.8
ArPhCH+/• per 1σ     5.6  
ArPhCH•/– per 1σ       7.4
ArCH2+/• per 1σ     9.3  
ArCH2•/– per 1σ       13.5
a

The first two lines are from this work (Table 1 and SI Section 7); the remaining values are from ref (70).