Comparison of the UV-vis data of O2−(2p) → Co3+(eg) and O2−(2p) → Co3+(t2g) peak maxima obtained from Co3O4 NPs of different sizes with literature data.
| Size [nm] | O2−(2p) → Co3+(eg) [nm] | O2−(2p) → Co3+(t2g) [nm] | Morphology | Source |
|---|---|---|---|---|
| 31.3 | ∼500 | ∼775 | Irregular | Makhlouf et al.58 |
| 22 | 441 | 756 | Thin film | Jiang et al.55 |
| 15.8 | ∼425 | ∼725 | Irregular | Makhlouf et al.58 |
| 10.9 | 390 | 677 | Cuboid NPs | This work |
| 4.7 | 376 | 669 | Spherical NPs | This work |
| 2.8 | 369 | 664 | Spherical NPs | This work |