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. 2023 Jul 4;5(15):3942–3954. doi: 10.1039/d3na00032j

Comparison of the UV-vis data of O2−(2p) → Co3+(eg) and O2−(2p) → Co3+(t2g) peak maxima obtained from Co3O4 NPs of different sizes with literature data.

Size [nm] O2−(2p) → Co3+(eg) [nm] O2−(2p) → Co3+(t2g) [nm] Morphology Source
31.3 ∼500 ∼775 Irregular Makhlouf et al.58
22 441 756 Thin film Jiang et al.55
15.8 ∼425 ∼725 Irregular Makhlouf et al.58
10.9 390 677 Cuboid NPs This work
4.7 376 669 Spherical NPs This work
2.8 369 664 Spherical NPs This work